Incoprea Theory
Vol. XXVII · 89

Theory 10/Molecular & anomalous/Supercooled water

Supercooling Is Entropy Against Relaxation

The claim

Supercooled water's anomalous slowdown is set by the ratio of configurational entropy to relaxation time, so viscosity diverges where entropy becomes small.

01Mechanism

Flow requires accessible configurations; as they vanish, relaxation slows sharply.

02Prediction

Relaxation should track the ratio.

03Refutation

Relaxation tracking temperature alone would remove entropy.