Incoprea Theory
Vol. XXVII · 89

Theory 01/Molecular & anomalous/Density anomaly

The Density Maximum Is a Lifetime Ratio

The claim

The temperature of water's density maximum is set by the ratio of hydrogen-bond lifetime to collision rate, so the anomaly shifts when that ratio is changed by pressure or solutes.

01Mechanism

Density depends on how much open tetrahedral order survives; the lifetime relative to collision determines the equilibrium fraction.

02Prediction

The maximum should shift with pressure as the lifetime changes.

03Refutation

A fixed maximum across pressures would remove the kinetic argument.